What are Class 4 flammable solids examples?
Daniel Moore
Published Jan 12, 2026
344.1 Definition
- Hazard Class 4 consists of three divisions:
- Examples of flammable solids include certain metallic hydrides, metallic sodium and potassium, oily fabrics, processed metals, matches, and nitrocellulose products.
- The following conditions apply:
What is a Class 4 flammable?
Class 4 Flammable solids; substances liable to spontaneous combustion; substances which, in contact with water, emit flammable gases.
What is a Class 4 hazardous material?
Class 4 Flammable Solid. Class 4 materials undergo combustion without outside changes to density or pressure. They are also prone to combustion without the assistance of chemical accelerants.
What is included in Class 4.1 flammable solids?
4.1 Flammable Solids: Solid substances that are easily ignited and readily combustible (nitrocellulose, magnesium, safety or strike-anywhere matches). 4.2 Spontaneously Combustible: Solid substances that ignite spontaneously (aluminium alkyls, white phosphorus).
What are examples of flammable solids?
Examples of flammable solids include certain metallic hydrides, metallic sodium and potassium, oily fabrics, processed metals, matches, and nitrocellulose products.
21 related questions foundWhat is a Class 4 Division 4.1 hazardous material?
Class 4.1 – Flammable solids, etc.
Some are self-reactive, and are liable to break down chemically, if they get above certain temperature, or are subjected to shock etc. They may then decompose explosively, or burn vigorously, or produce toxic gases or vapors.
What are examples of flammable liquids?
Flammable: A liquid with a flash point under 100°F is considered flammable. Examples: gasoline, acetone, toluene, diethyl ether, alcohols. Hazard: May produce ignitable vapors at normal ambient temperatures.
What is the dangerous goods class for flammable solids?
Class 4.2: Flammable solids.
Spontaneously Combustible material is a pyrophoric material, which is a liquid or solid that can ignite within five (5) minutes after coming in contact with air or a self-heating material that when in contact with air and without an energy supply is liable to self-heat.
What class is flammable liquids?
Flammable liquids are classified by NFPA as Class I, which are further sub- classified, based upon additional criteria that affect fire risk, as Class IA, Class IB and Class IC - these liquids have flash points below 100 ºF (37.8 ºC) or less.
How many divisions are there in Class 4 flammable solids?
Generic Types: Division 4.1 self-reactive materials are assigned to a generic system consisting of seven types. A self-reactive substance identified by technical name in the Self-Reactive Materials Table in 49CFR 173.224 is assigned to a generic type in accordance with that Table.
What are the 4 hazard categories?
4 Types of Workplace Hazards
- Physical Hazards. Physical hazards are the most common type of workplace hazards. ...
- Biological Hazards. ...
- Ergonomic Hazards. ...
- Chemical Hazards.
What is Class 4 of the IMDG Code?
Class 4 - Flammable Solids or Substances
4.3 Substances which, in contact with water, emit flammable gases.
Is Cardboard a flammable solid?
Can Cardboard Boxes be stored in Flammable Cabinets? The short answer is no. Under no circumstances should you store flammable materials such as paper or cardboard alongside flammable and hazardous materials.
What solid elements are flammable?
Flammable and Combustible Solids
Flammable solids often encountered in the laboratory include alkali metals, magnesium metal, metallic hydrides, some organometallic compounds, and sulfur. Many flammable solids react with water and cannot be extinguished with conventional dry chemical or carbon dioxide extinguishers.
Which is the following is a concern when handling or transporting Class 4 flammable solids?
Class 4 Dangerous Goods are flammable solids. This category of hazardous cargo represents substances which are liable to spontaneous combustion and goods that emit flammable gases when they come into contact with water. Metal powders are particularly hazardous as they are more difficult to extinguish when on fire.
Is coal a flammable solid?
Fire and Explosion Hazards: Solid coal is not readily combustible but can be ignited through sustained contact with an open flame.
Is wood a flammable solid?
A combustible material is a solid or liquid than can be easily ignited and burned. OSHA, DOT, and other federal regulations, apply specific technical definitions to this term. Combustible solids are those capable of igniting and burning. Wood and paper are examples of such materials.
Are oranges flammable?
Yes, they are. Even more so than regular citrus fruits. These citrus fruits contain a group of chemicals called Limonene that causes high temperatures that explode and catch fire.
Is vinegar flammable?
Generally vinegar is not flammable. While there are elements in vinegar that are flammable, the high water content of household vinegar keeps it from being flammable. However, chemistry isn't always that simple.
What is the most flammable?
1) Chlorine Trifluoride is the most flammable gas
Of all the dangerous chemical gases, chlorine trifluoride is known to be the most flammable. It is a colorless and extremely reactive gas that can burn through concrete and gravel.
What are the two types of flammable solids?
There are two categories of flammable solids: category 1 materials are rapidly burning metals and compounds very resistant to being extinguished by water; category 2 materials are slower burning metals and compounds that are susceptible to extinguishment by water.
Is a candle a flammable solid?
A candle is an ignitable wick embedded in wax, or another flammable solid substance such as tallow, that provides light, and in some cases, a fragrance.
What is a Class 5 hazardous material?
Hazard Class 5 consists of two divisions: Division 5.1, Oxidizing Substances. A material that may, generally by yielding oxygen, cause or enhance the combustion of other materials. Division 5.2, Organic Peroxides.
Can flammable solids spontaneously combust?
SUBSTANCES LIABLE TO SPONTANEOUS COMBUSTION; SUBSTANCES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES.